Monday, 23 February 2015

ANIMAL HUSBANDRY AND VETERINARY SCIENCE – 2003

       Time allowed:  3 hours    Maximum Marks: 200

Candidates should attempt Questions 1 and 5 which are compulsory, and ay THREE of the remaining questions selecting at least ONE question from each Section.

SECTION A

1.       Write short notes on any four of the following  in not more than 150 words:
(a)    Feed additives and feed supplements
(b)   Vitamin A and Vision
(c)    TDN and starch equivalent. Write their relative efficiency.
(d)   What is hay silage and how are they made?
(e)   Hormonal control of mammary gland of cow.

2.       Classify mineral required by animals. Discuss the factors affecting absorption of calcium and phosphorus. Write the deficiency symptoms of calcium and phosphorus. In dairy animals. Discuss the role of Vitamin D in calcium and phosphorus assimilation.

3.       (a) Give a critical review of various feeding standards along with their merits and limitations.
(b) Discuss various methods of measuring feed energy.

4.       Discuss the following:
(a)    Structure of female genetalia of a buffalo and write the function of each organ.
(b)   Metabolic disorders due to imbalance feeding.
(c)    Give composition of two prominent semen extenders commonly used.
(d)   Milk replacer and calf starter. Give on composition of each.

CHEMISTRY – 2003, PAPER- I, SECTION B

                            Time Allowed:   Three Hours      Maximum marks: 200

Candidates should attempt Questions 1 and 5 which are compulsory and any THREE of the remaining questions selecting at least ONE question from each Section. Assume suitable data. If considered necessary, and indicate the same clearly.
  SECTION B
5.       Answer any four of the following:

(a)     Give an account of the red-ox and precipitation reactions in liquid ammonia.
(b)   What is chelate effect?
(c)    What are fluxional molecules? Give two examples. How are they characterized?
(d)   Explain the variation of magnetic moments within the lanthanides.
(e)   Identify the various physical pathways by which a phone excited molecule undergoes deactivation.

6.       (a)  Discuss the structural aspects of metal-olefin and metal- alkyne complexes giving experimental evidences, and metal- alkyne complexes giving experimental evidences.
         (b) Discuss the salient features of molecular orbital theory and discuss its use in explain in the bonding in N₂ , O₂ and HF molecules.

7.       (a) What are metal atom clusters? Discuss the structure and bonding of two metal clusters with M-M single bond and M- M multiple bonds.
          (b) Assign the observed electronic absorption bands of [Ni (H₂ₒ) ₆] ²+ and [Cr (OX) ₃]³ - and explain on the basis of crystal field theory.

8.       (a) Discuss in detail the mechanism of oxygen transport in biological systems.
         (b) Give an account of the linkage isomerism and the various factors stabilizing the isomers. Choose suitable examples.
 

CHEMISTRY – 2003, PAPER- I, SECTION A

               Time Allowed:   Three Hours      Maximum marks: 200

Candidates should attempt Questions 1 and 5 which are compulsory and any THREE of the remaining questions selecting at least ONE question from each Section. Assume suitable data. If considered necessary, and indicate the same clearly.

SECTION A

1.       Answer any four of the following:

(a)    Explain the principle of ion selective electrodes. What are their applications?
(b)   What is Born-haber cycle? What is its use?
(c)    What are quantum numbers? What are their significances?
(d)   Write a note on liquefaction of gases.
(e)   What are reverse reactions? Derive the rate equation for reverse reaction.

2.       (a) State phases rule and explain the terms involved draw the phase diagram of a binary system of partially miscible liquids.
          (b) Deduce a pressure- volume relationship in reversible adiabatic expansion of an ideal gas.

3.       (a) What are fuel cells? Describe the constriction and working of a fuel cell?
            (b) Discuss the transition state theory of reaction rates.

4.       (a) Describe the experimental set up for the measurement of emf of a cell.

           (b)  What is an adsorption isotherm? How are Langmuir and BET isotherms obtained?  What are their characteristics?

MECHANICAL ENGINEERING – 2003,PAPER – II ,Section B

                    Time Allowed: Three Horus      Maximum marks: 200
Candidates should attempt Questions 1 and 5 which are compulsory and any THREE of the remaining questions selecting at least ONE question from each Section.
If any data is considered insufficient, assume suitable valur.
  
SECTION B
5.       Answer any four parts:

(a)    The evaporator and condenser temperatures in a reverse Carnot refrigeration cycle of 1 TR capacity are 263 K and 313LK respectively. The outlet of compression is saturated vapour and into to turbine is saturated liquid. Find the mass flow rate, work done condenser heat rejection and COP. Properties of refrigerant at saturation in SI units are as follows:

t (K)
hf
hg
S f
Sg
263
154.056
1450.22
0.82965
5.755
313
390.587
1490.42
1.64377
5.1558

(b)   Air enters a cooling coil at 30˚C, 75 % relative humidity. The apparatus dewpoint is 12˚ c and bypass factor is 0.15. Find the temperature and humidity ratio at outlet of cooling coil. If mass flow rate of air is 10 kg / s, find the condensate rate and cooling capacity of cooling coil. The partial pressures of water vapour at 12˚ C and 30˚C are 1.4017 and 4.2431 kPa respectively. Atmospheric pressure is 101.325 kPa. Enthalpy of condensate at 12˚C = 50.24 kJ / kg.
(c)    Explain the nomenclature Rabc for CFCs and inorganic compounds. What is meant by ozone depletion? Name at least two refrigerants that do not cause it.
(d)   State Buckingham’s  theorem. Using Buckingham’s  theorem obtain an expression for drag force on a partially submerged body moving with a relative velocity V in fluid, the other variables being linear dimension L height of surface roughness K, the fluid density ƿ and gravitational accelerating.
(e)   Discuss the criteria for the selection of site for steam and hydroelectric power plants.

6.       (a) A refrigeration system of 10 TR cooling capacity has condenser and evaporator temperatures of 45˚C and – 20 ˚C respectively. The vapour leaving the evaporator sub cools the liquid leaving the condenser from 45 ˚C to 25˚C. Draw schematic diagram and T.S fiagram considering isentropic compression, isobaric heat absorption and rejection. Determine mass flow rate, compressor work. Condenser heat rejection and COP. Use vapour specific heat at condenser pressure to find COP. USE vapour specific heat at condenser pressure to fin adiabatic discharge temperature and enthalpy. The properties in SI units at saturation are:


hf
hg
sg
C pg
Cpf
-20˚ C
17.8
178.7
0.7088
0.61
-
45˚C
79.7
204.9
0.6812
0.755
1.02

                        (b) Define thermodynamic wet bulb temperature t* and show that humidity ratio may be expressed as

W = W* h* fg  - 1.005 (t- t*)    /   hg (t) – h*f

Where enthalpy of moist air is expressed as h= 1.005 (t) + hg (t).

7.       (a)  Diabatic flow of dry air takes place through a frictionless constant area duct. At some particular section of the duct, the Mach number is 4.0 while stagnation temperature and static pressure are 280 K and 0.5 bar respectively. Calculate the stagnation temperature. Static and stagnation pressures at a section where the Mach numbers is 2.0 also find the amount of heat transfer which causes this reduction Mach number. Take Cp= 1.005 kJ/ kg and γ = 1.4.
M
P /ᵖP*
T/ T*
Tₒ/ Tₒ*
Pₒ / Pₒ*

2.0
0.364
0.529
0.793
1.503
4.0
0.1026
0.168
0.589
8.277
  
                                                                                                                 
          (b) Explain what you understand by specific speed of a turbo machine. Give its importance.
Calculate the specific speeds of the following cases:

             (i)                  A 2500 kW gas turbine is running at a speed of  18000 RPM. The entry and exit conditions of the gas are T₁ = 1100 K₁ P₁ =60 bar, P₂ = 30 bar.
            (ii)                A centrifugal compressor develops a pressure ratio of 1.5 while running at 24000 RPM and discharging 2.0 kg/s of air, the entry conditions are P₁ =1.0, T₁ = 290K.
1 or both cases take
γ + 1.4, R = 287 J / kg – k, Cᵨ =1.005 kJ / kg –k.

8.       (a) Explain clearly, “heat rate curve’ and “ Incremental rate curve’. Show that the incremental rate curve crosses the heat rate curve at the lowest value of heat rate.
The incremental fuel costs for two generating units A and B of a plant are given by
dF a / dPa  = 0.065 Pa + 25
dF b / dPb = 0.08 Pb + 20
where F is fuel cost in Re / hr and P is power output in MW. Find –

(i)                  The economic loading of the two units when the total load supplied by the power plant is 160 MW.
(ii)                The loss in fuel cost/ hr if the load is shared equally by the units.

(b) Discuss the importance of the terms, capacity factor and use factor from the economic point of view of the power plant.

A power station is said to have a sue factor of 50% and a capacity factor of 45%. How many hours the plant did not operate during the year?

MECHANICAL ENGINEERING – 2003,PAPER – II ,Section A

                              Time Allowed: Three Horus      Maximum marks: 200
Candidates should attempt Questions 1 and 5 which are compulsory and any THREE of the remaining questions selecting at least ONE question from each Section.
If any data is considered insufficient, assume suitable valur.

Newton may be converted to kg using the equality 1 kolonewton (1 kN) = 100 kg, if found necessary.
All answers should be in SI units.
Take: 1 kcal = 4. 187 kJ and 1 kg /cm³ = 0.98 bar
1 bar = 10⁵ Pascals
Universal gas constant = 8314.6 J/ k mol – k

Section A
1.       Answer any four parts:

(a)    (i) Two cannot engines work in series between the source and sink temperatures of 600 K and 300 K, if both engines develop equal power, determine the intermediate temperature.
               (ii) Show that the compression ratio for the maximum work to be done per kg of air in an Otto cycle between upper and lower limits of absolute temperatures T₃ and T₁ is given by the expression
R= (T₃ / T₁)    1 / 2(γ-1) 
(b)   (i) An ideal gas is heated at constant volume until its temperature is 3 times the original temperature, then it is expanded isothermally till is reaches its original pressure, the gas is then restored to its original state. Determine the expression of net work done.
               (ii) 300 kj / sec of heat is supplied at a constant fixed temperature of 290˚C to a heat engine. The heat rejection takes place at 8.5˚C. The following results were obtained:
                              (I)                 215 kJ/ s of heat is rejected
                             (II)               150 kJ/ s of heat is rejected
                            (III)             75 kJ/ s of heat is rejected
Using Clausius inequality which of the results report a reversible cycle of irreversible cycle, or impossible result? 
(c)    (i) What is petrol injection? What are its advantages and disadvantages?
                  (ii) What is petrol injection? What are its advantages and disadvantages?

(d)   Make a detailed comparison of SI and CI engines with respect to basic cycle, fuel, introduction of fuel in the cylinder, ignition, compression ratio and weight.

(e)   Two parallel flat plates of equal area 0.5 m² each face each other. These are at 1000 K and 500 k respectively. Shape factor between them F₁₂ = F ₂₁ = 0.285. These are placed in room whose walls are at 300 k. Find radiation heat transfer rate between the plates and between the plates and wall. Assume that outer part of both the plates is insulated.
Stefan- Boltzmann constant = 5.67 x 10 ⁻⁸ W/ K ⁴ - m³.

2.       (a) What is detonation? Factors leading to increase detonation in SI engines tend to reduce knock states above in the light of differences in their nature. Indicate the methods to reduce knock in CI engines.

(b) Determine the diameter of a fuel orifice for a 4-stroke engine working on diesel cycle developing 18 kg/ kw-hr fuel of 30˚ API. The duration of the crank injection is 30˚ of crank travel the fuel injection pressure is 125 bars and the combustion chamber pressure is 35 bars. Take velocity coefficient as 0.9 and
Ƿ = 141.5 / 131.5 + ˚API

3.       (a) (i) What is stoichiometric air requirement and excess air factor?

                                   (ii) What do you understand by higher calorific value and lower calorific value?   Explain the methods to measure them
                            (b) Determine the air-fuel ratio at 6000 m altitude in a carburetor adjusted to give an air-fuel ratio of 15: 1 at sea level where the air temperature is 300 k and pressure of 1.013bar.
The temperature of air decreases with altitude and is given by the expression

t =ts – 0.0065 h.
Where h is altitude in meters and ts is the temperature at sea level in ˚C.
The air pressure decreases with altitude as per the relation
 H= 19220log 10 (1.013 /P)
Where, p is in bar.
What remedies would you suggest to compensate for the decrease in air fuel ratio at high altitudes? Discuss them giving justification

4.       (a) show that the governing equation for temperature distribution in a fin of uniform cross –section is given by

d² Ѳ/ dx² - m² Ѳ = 0
Where, Ѳ = T – T, and m² = hP/ kA.
Further, show that the solution for boundary conditions Ѳ = Ѳₒ at X = 0 and Ѳ = Ѳ ₁at x = L is
Ѳ = [Ѳ₁ sin h mx + Ѳₒ sin h m (L – X)] / sin h mL.

                           (b) Water flows in the tube and brine flows in the annulus of a double –tube heat exchanger. Water at the rate of 0.015 kg/s is cooled from 30˚ C to 20˚C and temperature of brine increases from - 15˚C to - 5˚C. The inner and outer diameters of water of water-carrying tube are 25mm and 30 mm respectively, and thermal conductivity of metal is 45 W/ m –K. The convective heat transfer coefficients on the brine and water, side are 2700 and 2100 W/ m² - K respectively. Find 

 Overall heat transfer coefficient and then the length of the heat exchanger for parallel flow and counter flow and counter flow. Specific heat of water = 4.18kJ / kg –k.
                                                                                                                                                                                               

Sunday, 22 February 2015

MEGHANICAL ENGINEERING, PAPER- I – 2003, SECTION B

                     Time Allowed: three Hours                  Maximum Marks: 200
Candidates should attempt Questions 1 and 5 which are compulsory, and any THREE of the remaining questions selecting at least ONE question from each Section. Assume suitable data, if considered necessary, and indicate the same clearly. Newton may be converted to kg using the relation 1 kilonewton (1 kN) = 100 kg if found necessary.    

SECTION B

5.       Answer any  four of the following (each answer should conform to a limit of around 150 words)
                  (a)    (i) Explain the differences between tolerance and allowance.
(ii) Discuss the terms ‘roughness’ weaviness’ and ‘lay’

(b)   (i) Why is springback important in cold forming?
(ii) Why most press forging often employ heated dies?
(iii) What is 3-2-1 concept related to jig and fixture design?

(c)    (i) What are various types of valve? What do you personally gain from value engineering?
(ii) Give some examples of waiting time situations existing in industry.

(d)   (i) Draw figure showing four waiting line structures.
(ii) What types of distributions are assumed for arrivals and services?
(iii) In a single channel waiting line if μ = λ, what will be the utilization factor and mean waiting time for a customes before being served μ = Av. No. of services provided per unit time and λ = Av. No. of arrivals per unit time.

                    (e)   (i) Write the purpose of subroutine in a computer program including its general form.

(ii) Name three types of plotters used in computers to produce hard copy.

6.       (a) (i) write the circuits which make control loop unit (CLU) in CNC machine

(ii) What is meant by the following codes?
g 9 0
m 0 3
      (b)  DC servomotor is coupled directly to a lead screw which drives the table of an NC machine tool. A digital encoder, which emits 500 pulses per revolution, is mounted on the other end of the lead screw. If the lead screw pitch is 5 mm and motor rotates at 800 rpm calculate.

(i)                  The linear velocity of the table
(ii)                The basic length unit (BLU) of the N.C system
(iii)               The frequency of the pulses transmitted by the encoder. 1 pulse = 1 BLU.

        (c)   (i) Explain with a figure stylus profile device for measuring surface roughness.
                    (ii) How Ra (arithmetic mean) value of surface roughness is defined.

7.       (a) Florence Health INC is a Professional II nursing home aspiring to become Professional I nursing home. Administrator prepares the following list of activities:

Activity
Predecessor’s Activity
Time estimates  (Weeks)

to
tm
tp
B. Build Facility
None
20
24
30
F. Safety Inspection
B
2
3
4
C. Install Equipment
B
8
16
20
D.Recruit Staff
None
2
2
3
E. Train Staff
D
4
5
6
A. Perform Pilot
C. E. F
6
5
9

Draw the PERT diagram and show the critical path (consider β- distribution) what is Time / Cost tradeoff?
           (b) Solve the assignment problem represented by the matrix given below:


a
b
c
d
e
F
A
9
22
58
11
19
27
B
43
78
72
50
63
48
C
41
28
91
37
45
33
D
74
42
27
49
39
32
E
36
11
57
22
25
18
F
3
56
53
31
17
28

8.       (a) (i) Discuss the principles and applications of slip gauges. What are the different grades of accurac
            (ii)  Draw Merchant’s circular force diagram and write the assumptions.

       (b) Solve the following linear programming problem:

Maximize      z= 3x₁ + 2x₂ + 5x₃
Subject to
X₁ + 2X₂   + X₃ ≤ 430
3X₁ + 2X₃ ≤ 460
X₁ + X₂ ≤ 420
X₁ ≥ 0, X₂ ≥ 0, X₃ ≥ 0.